Thermodynamic properties of the Zn−Pb−In ternary system in dilute liquid zinc solutions
Identifieur interne : 000B13 ( Main/Exploration ); précédent : 000B12; suivant : 000B14Thermodynamic properties of the Zn−Pb−In ternary system in dilute liquid zinc solutions
Auteurs : RBID : ISTEX:11663_1971_Article_BF02917547.pdfAbstract
Electromotive force measurements were conducted on ternary Zn−Pb−In solutions having zinc concentrationsXZn=0.03, 0.05, 0.07, and 0.1. Special attention was paid to the effect of the addition of indium and lead on the Ln γZn value at 714°, 757°, and 805°K. These data served to determine the interaction parameters ∈ZnIn and ∈PbZn from the$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots over the indicated ranges of temperatures. The end points in ln γZn vs XPb and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots were taken from previous measurements on the Zn−In and Zn−Pb systems. The values of ln γZn and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 $$ in Zn−Pb−In dilute solutions were carried out by means of Krupkowski’s formulae. The influence of the Zn−Pb system in Zn−Pb-Me ternary solutions with a preponderant content of lead was analyzed whenMe=Bi, Cd, Sn, and Sb.
DOI: 10.1007/BF02917547
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Moser</name><affiliation wicri:level="1"><mods:affiliation>the Institute for Metal Research, Polish Academy of Sciences, Krakow, Poland</mods:affiliation><country xml:lang="fr">Pologne</country><wicri:regionArea>the Institute for Metal Research, Polish Academy of Sciences, Krakow</wicri:regionArea><wicri:noRegion>Krakow</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:11663_1971_Article_BF02917547.pdf</idno><date when="1971">1971</date><idno type="doi">10.1007/BF02917547</idno><idno type="wicri:Area/Main/Corpus">000C49</idno><idno type="wicri:Area/Main/Curation">000C49</idno><idno type="wicri:Area/Main/Exploration">000B13</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">Electromotive force measurements were conducted on ternary Zn−Pb−In solutions having zinc concentrationsXZn=0.03, 0.05, 0.07, and 0.1. Special attention was paid to the effect of the addition of indium and lead on the Ln γZn value at 714°, 757°, and 805°K. These data served to determine the interaction parameters ∈ZnIn and ∈PbZn from the$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots over the indicated ranges of temperatures. The end points in ln γZn vs XPb and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots were taken from previous measurements on the Zn−In and Zn−Pb systems. The values of ln γZn and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 $$ in Zn−Pb−In dilute solutions were carried out by means of Krupkowski’s formulae. The influence of the Zn−Pb system in Zn−Pb-Me ternary solutions with a preponderant content of lead was analyzed whenMe=Bi, Cd, Sn, and Sb.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="d9b273c7fddc20d990eaca9b10961d2850a39392"><titleInfo lang="eng"><title>Thermodynamic properties of the Zn−Pb−In ternary system in dilute liquid zinc solutions</title></titleInfo><name type="personal"><namePart type="given">Z.</namePart><namePart type="family">Moser</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>the Institute for Metal Research, Polish Academy of Sciences, Krakow, Poland</affiliation></name><typeOfResource>text</typeOfResource><genre>Process Metallurgy</genre><genre>Original Paper</genre><originInfo><publisher>Springer-Verlag, New York</publisher><dateCreated encoding="w3cdtf">1970-07-27</dateCreated><dateValid encoding="w3cdtf">2008-06-06</dateValid><copyrightDate encoding="w3cdtf">1971</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">Electromotive force measurements were conducted on ternary Zn−Pb−In solutions having zinc concentrationsXZn=0.03, 0.05, 0.07, and 0.1. Special attention was paid to the effect of the addition of indium and lead on the Ln γZn value at 714°, 757°, and 805°K. These data served to determine the interaction parameters ∈ZnIn and ∈PbZn from the$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots over the indicated ranges of temperatures. The end points in ln γZn vs XPb and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 vs X_{Pb} $$ plots were taken from previous measurements on the Zn−In and Zn−Pb systems. The values of ln γZn and$$(ln\gamma _{Zn} )_{X_{Zn} } \to _0 $$ in Zn−Pb−In dilute solutions were carried out by means of Krupkowski’s formulae. The influence of the Zn−Pb system in Zn−Pb-Me ternary solutions with a preponderant content of lead was analyzed whenMe=Bi, Cd, Sn, and Sb.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>MMTB</title></titleInfo><titleInfo><title>Metallurgical and Materials Transactions B</title><partNumber>Year: 1971</partNumber><partNumber>Volume: 2</partNumber><partNumber>Number: 8</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1971-08-01</dateIssued><copyrightDate encoding="w3cdtf">1971</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Materials Science</topic><topic>Manufacturing, Machines, Tools</topic><topic>Metallic Materials</topic><topic>Operating Procedures, Materials Treatment</topic><topic>Characterization and Evaluation of Materials</topic><topic>Numerical and Computational Methods in Engineering</topic></subject><identifier type="issn">1073-5615</identifier><identifier type="issn">Electronic: 1543-1916</identifier><identifier type="matrixNumber">11663</identifier><identifier type="local">IssueArticleCount: 56</identifier><recordInfo><recordOrigin>ASM International & TMS-The Minerals, Metals and Materials Society, 1971</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF02917547</identifier><identifier type="matrixNumber">Art21</identifier><identifier type="local">BF02917547</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>2175</start><end>2183</end></extent></part><recordInfo><recordOrigin>ASM International & TMS-The Minerals, Metals and Materials Society, 1971</recordOrigin><recordIdentifier>11663_1971_Article_BF02917547.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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